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Reviewed CSCA Chemistry question · Standard

Which of the following compounds would react with an aqueous solution of bromine at room temperature in the dark?

  1. Ethane
  2. Ethene
  3. Ethanol
  4. Chloroethane
Show the answer and explanation

Correct answer

B. Ethene

Principle or equation

Alkenes contain a carbon-carbon double bond, which undergoes addition reactions with bromine water, decolorizing it. Alkanes, alcohols, and haloalkanes do not react under these conditions.

Why this answer is correct

Ethene (C2H4) has a double bond. Bromine adds across the double bond to form 1,2-dibromoethane, so the orange/brown bromine water is decolorized. Ethane is saturated and requires UV light for substitution. Ethanol and chloroethane do not react with bromine water at room temperature in the dark.

Example

Bubble ethene gas into bromine water; the color changes from orange to colorless.

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