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Reviewed CSCA Chemistry question · Standard

A student dissolves 0.0200 mol of a strong monoprotic acid HA in enough water to make 400.0 mL of solution. What is the pH of the resulting solution? Assume complete dissociation.

  1. 1.30
  2. 1.70
  3. 2.00
  4. 2.30
Show the answer and explanation

Correct answer

A. 1.30

Principle or equation

pH = -log[H+]. For a strong monoprotic acid that fully dissociates, [H+] equals the acid concentration, which is moles of acid divided by volume in liters.

Why this answer is correct

Moles of HA = 0.0200 mol. Volume = 400.0 mL = 0.400 L. Concentration = 0.0200 / 0.400 = 0.0500 M. Since HA is strong and monoprotic, [H+] = 0.0500 M. pH = -log(0.0500) = 1.301, which rounds to 1.30.

Example

If 0.0100 mol of HCl is dissolved to make 250.0 mL, concentration = 0.0100/0.250 = 0.0400 M, pH = -log(0.0400) = 1.40.

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