CSCAPrep
Reviewed CSCA Chemistry question · Easy

A sample of a pure substance is cooled from 200°C to -50°C at 1 atm. During cooling, it condenses from gas to liquid at 120°C and then freezes from liquid to solid at 10°C. Which of the following statements correctly describes the changes that occur as the substance cools from 150°C to 0°C?

  1. The substance remains a gas throughout this temperature range.
  2. The substance changes from gas to liquid at 120°C, then remains liquid until 10°C, then changes to solid.
  3. The substance changes from liquid to solid at 10°C, then remains solid.
  4. The substance changes from gas to solid directly at 120°C.
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Correct answer

B. The substance changes from gas to liquid at 120°C, then remains liquid until 10°C, then changes to solid.

Principle or equation

A pure substance has characteristic phase transition temperatures at a given pressure. During cooling, the gas condenses to liquid at the condensation point, and the liquid freezes to solid at the freezing point.

Why this answer is correct

At 150°C, the substance is above its condensation point (120°C), so it is a gas. As it cools to 120°C, it condenses to liquid. Between 120°C and 10°C, it remains liquid. At 10°C, it freezes to solid. Therefore, the correct description is that it changes from gas to liquid at 120°C and remains liquid until 10°C, then changes to solid.

Example

For water at 1 atm, cooling steam from 150°C to -20°C: gas condenses at 100°C, liquid freezes at 0°C. Similarly, the given substance has a condensation point at 120°C and freezing point at 10°C.

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