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Reviewed CSCA Chemistry question · Standard

A rigid container holds 0.400 mol of an ideal gas at a pressure of 1.50 atm and a temperature of 320 K. The gas is heated to 400 K while the volume remains constant. What is the new pressure in atm?

  1. 1.20 atm
  2. 1.50 atm
  3. 1.88 atm
  4. 2.00 atm
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Correct answer

C. 1.88 atm

Principle or equation

For a fixed amount of gas at constant volume, pressure is directly proportional to absolute temperature: P1/T1 = P2/T2.

Why this answer is correct

Given P1 = 1.50 atm, T1 = 320 K, T2 = 400 K. P2 = P1 × (T2/T1) = 1.50 × (400/320) = 1.50 × 1.25 = 1.875 atm ≈ 1.88 atm.

Example

If a gas at 300 K and 1.00 atm is heated to 600 K at constant volume, new pressure = 2.00 atm.

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