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Reviewed CSCA Chemistry question · Standard

A mixture contains solid iodine and solid sodium chloride. Iodine sublimes readily when heated gently, while sodium chloride does not. Which method is most appropriate to separate and obtain pure iodine from the mixture?

  1. Add water, filter, and evaporate the filtrate
  2. Heat the mixture gently and collect the sublimed iodine on a cold surface
  3. Add water, then add silver nitrate solution and filter
  4. Dissolve in ethanol and filter
Show the answer and explanation

Correct answer

B. Heat the mixture gently and collect the sublimed iodine on a cold surface

Principle or equation

Sublimation is a separation technique for substances that can change directly from solid to gas upon heating, leaving non-sublimable impurities behind.

Why this answer is correct

Iodine sublimes when heated, forming purple vapor that can be collected and cooled back to solid on a cold surface. Sodium chloride does not sublime, so it remains in the container. This directly separates and purifies iodine.

Example

A mixture of iodine and sand can be separated by heating; iodine vapor condenses on a cold watch glass, leaving sand behind.

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