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Reviewed CSCA Chemistry question · Standard

对于反应N2(g) + 3H2(g) ⇌ 2NH3(g) ΔH < 0,下列哪种措施能使平衡向正反应方向移动?

  1. 升高温度
  2. 增大容器体积
  3. 加入催化剂
  4. 增大N2的浓度
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Correct answer

D. 增大N2的浓度

Principle or equation

勒夏特列原理:改变影响平衡的条件,平衡向减弱这种改变的方向移动。

Why this answer is correct

增大反应物N2浓度,平衡向正反应方向移动。升高温度平衡向吸热方向(逆反应)移动;增大体积即减小压强,平衡向气体分子数增多的方向(逆反应)移动;催化剂不影响平衡。

Example

合成氨工业中,增大N2或H2浓度可提高转化率。

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