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Reviewed CSCA Chemistry question · Easy

常温下,将 0.04 g 氢氧化钠固体溶于水配成 1 L 溶液,则该溶液的 pH 为多少?(NaOH 摩尔质量为 40 g/mol,忽略体积变化,25℃时 Kw=1.0×10^-14)

  1. 11
  2. 12
  3. 10
  4. 13
Show the answer and explanation

Correct answer

A. 11

Principle or equation

c(OH-) = n(NaOH)/V,pOH = -lg c(OH-),pH = 14 - pOH。

Why this answer is correct

n(NaOH) = 0.04 g / 40 g/mol = 0.001 mol;c(OH-) = 0.001 mol / 1 L = 0.001 mol/L;pOH = 3;pH = 14 - 3 = 11。

Example

若 0.08 g NaOH 配成 1 L 溶液,则 c(OH-) = 0.002 mol/L,pOH≈2.3,pH≈11.7。

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