常温下,将 0.04 g 氢氧化钠固体溶于水配成 1 L 溶液,则该溶液的 pH 为多少?(NaOH 摩尔质量为 40 g/mol,忽略体积变化,25℃时 Kw=1.0×10^-14)
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Correct answer
A. 11
Principle or equation
c(OH-) = n(NaOH)/V,pOH = -lg c(OH-),pH = 14 - pOH。
Why this answer is correct
n(NaOH) = 0.04 g / 40 g/mol = 0.001 mol;c(OH-) = 0.001 mol / 1 L = 0.001 mol/L;pOH = 3;pH = 14 - 3 = 11。
Example
若 0.08 g NaOH 配成 1 L 溶液,则 c(OH-) = 0.002 mol/L,pOH≈2.3,pH≈11.7。
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