在恒温恒容密闭容器中,发生反应:2NO2(g) ⇌ N2O4(g) ΔH < 0。达到平衡后,向容器中充入一定量的氦气(不参与反应),容器体积保持不变。则正反应速率将如何变化?
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Correct answer
C. 不变
Principle or equation
恒温恒容下充入惰性气体,反应物和生成物的浓度不变,因此正、逆反应速率均不变,平衡不移动。
Why this answer is correct
恒容条件下充入氦气,容器体积不变,各反应物和生成物的分压不变,浓度不变,所以正反应速率不变。
Example
恒容容器中充入稀有气体,反应体系中各物质浓度不变,速率不变。
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