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Reviewed CSCA Chemistry question · Standard

A solution is prepared by dissolving 0.025 mol of a strong diprotic acid H2A in water to make 500 mL of solution. What is the pH of the resulting solution? Assume complete dissociation.

  1. 1.00
  2. 1.30
  3. 2.00
  4. 1.70
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Correct answer

A. 1.00

Principle or equation

For a strong diprotic acid, each mole of H2A produces 2 moles of H+ ions. pH = -log[H+], where [H+] is the molar concentration of hydrogen ions.

Why this answer is correct

Calculate moles of H+: 0.025 mol H2A × 2 = 0.050 mol H+. Concentration [H+] = 0.050 mol / 0.500 L = 0.10 M. pH = -log(0.10) = 1.00.

Example

If 0.010 mol of H2SO4 is dissolved in 1.00 L, [H+] = 0.020 M, pH = 1.70.

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