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Reviewed CSCA Chemistry question · Easy

A sample of a pure substance is heated from -50°C to 200°C at 1 atm. The temperature remains constant at 0°C for a period, then rises, then remains constant at 100°C. Which of the following correctly describes the changes of state that occur?

  1. The substance melts at 0°C and boils at 100°C.
  2. The substance sublimes at 0°C and melts at 100°C.
  3. The substance freezes at 0°C and condenses at 100°C.
  4. The substance evaporates at 0°C and decomposes at 100°C.
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Correct answer

A. The substance melts at 0°C and boils at 100°C.

Principle or equation

At constant pressure, a pure substance changes state at fixed temperatures: melting (solid to liquid) and boiling (liquid to gas). Constant temperature during heating indicates a phase change.

Why this answer is correct

The temperature plateau at 0°C indicates a phase change from solid to liquid (melting), and the plateau at 100°C indicates a change from liquid to gas (boiling).

Example

For water, the melting point is 0°C and the boiling point is 100°C at 1 atm.

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