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Reviewed CSCA Chemistry question · Easy

A sample of a pure substance is heated from -100°C to 300°C at 1 atm. Its temperature remains constant at -30°C for a period, then rises, then remains constant at 150°C. Which of the following correctly describes the changes of state that occur?

  1. Melting at -30°C and boiling at 150°C
  2. Sublimation at -30°C and melting at 150°C
  3. Freezing at -30°C and condensation at 150°C
  4. Deposition at -30°C and boiling at 150°C
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Correct answer

A. Melting at -30°C and boiling at 150°C

Principle or equation

During heating at constant pressure, a pure substance's temperature remains constant at phase transition points. The first plateau corresponds to melting (solid to liquid) and the second to boiling (liquid to gas).

Why this answer is correct

The substance is initially solid. At -30°C, the temperature stops rising, indicating a phase change from solid to liquid (melting). After that, temperature rises until 150°C, where it plateaus again, indicating a phase change from liquid to gas (boiling).

Example

For water, heating from -20°C to 120°C shows a plateau at 0°C (melting) and at 100°C (boiling).

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